Search the Archive
  Home
  Welcome to
  Station Information
  Mathematical and
  Natural Sciences

  Astronomy
  Biology
  Chemistry
  Computer science
  Earth science
  Ecology
  Health science
  Mathematics
  Physics
  Statistics
  Applied Arts
  and Sciences

  Agriculture
 
Architecture
  Business
  Communication
  Education
  Engineering
  Family and
  consumer science

  Government
  Law
  Library and information
  science

  Medicine
  Politics
  Public affairs
  Software engineering
  Technology
  Transport
  Social Sciences
  and Philosophy

  Archaeology
  Economics
  Geography
  History
  History of science
  and technology

  Language
  Linguistics
  Mythology
  Philosophy
  Political science
  Psychology
  Sociology
  Culture and
  Fine Arts

  Classics
  Cooking
  Dance
  Entertainment
  Film
  Games
  Gardening
  Handicraft
  Hobbies
  Holidays
  Internet
  Literature
  Music
  Opera
  Painting
  Poetry
  Radio
  Recreation
  Religion
  Sculpture
  Sports
  Television
  Theater
  Tourism
  Visual arts and design

Kinetics


 
Kinetics is the study of the rate at which compounds react. This depends on several factors, including the area of contact between the materials, their concentrations, and the temperature at which the reaction takes place. For a reaction k A + m B → C + D, the rate is typically something of the form

d[C]/dt = k(T)[A]k'[B]m'

Here [X] denotes, for a reaction between liquids, gases, or solutes, the concentration of X; for a reaction taking place at a boundary it would denote something like moles per area of X. k(T) is a rate constant that depends on temperature. The exponents k' and m' are called orders and depend on the reaction mechanism, ie the sequence of steps (collisions) that the reaction takes place by, and in fact kinetics is one of the main ways of studying these. For a single-step reaction we would have

d[C]/dt = ke-Ea/RT[A]k[B]m

Here Ea is the activation energy, the energy per mole it is necessary for the molecules to have to react. Since at temperature T the molecules have energies according to a Boltzmann distribution, one can expect the proportion of collisions with energy greater than Ea to vary with e-Ea/RT. K has to do with stuff like the probability that molecules are in the right orientation, and of course dimensions.

For most multi-step reactions the rate is determined primarily by a single slow step, with preceding steps proceeding quickly to a state of rough equilibrium. In general, concentrations of species are never determined solely by a single process, and as reactions occur the products begin to undergo the reverse reaction to some extent. Thus reactions never proceed to 100% completion but rather to a state of chemical equilibrium where every step occurs at the same rate as its reverse.

The Arrhenius equation gives the quantitative basis of the relationship between the activation energy and the rate at which a reaction proceeds.








Site Partners

Easy Encyclopedia
Small Business Forum
Free Web Templates
Free Mortgage Quote

  This content from wikipedia is licensed under the GNU Free Documentation License